Hazard Overview

Health hazards: Exposure to high concentrations of vapor can cause headaches, drowsiness, ataxia, and irritation to the eyes, nose, and throat. Oral administration can cause nausea, vomiting, abdominal pain, diarrhea, drowsiness, coma, and even death. Long term skin contact can cause dryness and cracking of the skin.

Explosive hazard: This product is flammable and irritating.

Emergency measures

Skin contact: Remove contaminated clothing and thoroughly rinse the skin with soap and water.

Eye contact: Lift the eyelids and rinse with flowing water or saline solution. Seek medical attention.

Inhalation: Quickly leave the scene and move to a place with fresh air. Keep the respiratory tract unobstructed. If breathing is difficult, administer oxygen. If breathing stops, immediately perform artificial respiration. Seek medical attention.

Ingestion: Drink plenty of warm water and induce vomiting. Gastric lavage. Seek medical attention.

Fire protection measures

Hazardous characteristics: Flammable, its vapor can form explosive mixtures with air, and can cause combustion and explosion when exposed to open flames or high heat energy. Reacts violently when in contact with oxidants. In a fire scene, heated containers pose a risk of explosion. Its vapor is heavier than air and can spread to a considerable distance at lower levels. It will ignite and reignite when exposed to a source of fire.

Harmful combustion products: carbon monoxide, carbon dioxide.

Fire extinguishing method: Move the container from the fire scene to an open area as much as possible. Spray water to keep the fire container cool until the fire is extinguished. If the container in the fire has changed color or produced sound from the safety relief device, it must be evacuated immediately. Extinguishing agent: insoluble foam, dry powder, carbon dioxide, sand.

Emergency response to leakage

Quickly evacuate personnel from the contaminated area to a safe zone, isolate them, and strictly restrict their entry and exit. Cut off the fire source. It is recommended that emergency personnel wear self-contained positive pressure respirators and anti-static work clothes. Cut off the leakage source as much as possible. Prevent the flow into restricted spaces such as sewers and drainage ditches. Minor leakage: Absorb or absorb with sand or other non combustible materials. You can also rinse with a large amount of water, dilute the washing water, and put it into the wastewater system. Massive leakage: Construct embankments or dig pits to contain it. Cover with foam to reduce steam disaster. Transfer to a tanker or dedicated collector using an explosion-proof pump, and recycle or transport to a waste disposal site for disposal.

Handling and Storage

Precautions for operation: Closed operation, comprehensive ventilation. Operators must undergo specialized training and strictly adhere to operating procedures. It is recommended that operators wear filter type gas masks (half face masks), safety goggles, anti-static work clothes, and latex gloves. Keep away from sources of fire and heat, and smoking is strictly prohibited in the workplace. Use explosion-proof ventilation systems and equipment. Prevent steam leakage into the workplace air. Avoid contact with oxidants, acids, and halogens. During filling, the flow rate should be controlled and there should be a grounding device to prevent static electricity accumulation. Handle with care during transportation to prevent damage to packaging and containers. Equip with corresponding types and quantities of fire-fighting equipment and emergency response equipment for leaks. Empty containers may contain residual harmful substances.

Storage precautions: Store in a cool and ventilated warehouse. Stay away from sources of fire and heat. The storage temperature should not exceed 30 ℃. Keep the container sealed. It should be stored separately from oxidants, acids, halogens, etc., and avoid mixing storage. Adopt explosion-proof lighting and ventilation facilities. Prohibit the use of mechanical equipment and tools that are prone to generating sparks. The storage area should be equipped with emergency response equipment for leaks and suitable containment materials.

Contact control and individual protection

China MAC (mg/m3): 200 Former Soviet Union MAC (mg/m3): 10

TLVTN： OSHA   400ppm,985mg/m3; ACGIH 400ppm,983mg/m3  TLVWN： ACGIH   500ppm,1230mg/m3

Engineering control: The production process is sealed and fully ventilated. Provide safety shower and eye wash equipment.

Respiratory protection: Generally, no special protection is required. When exposed to high concentrations, a filtered gas mask (half face mask) can be worn.

Eye protection: Generally, no special protection is required. Safety goggles can be worn when exposed to high concentrations. Body protection: Wear anti-static work clothes.

Hand protection: Wear latex gloves. Other protections: Smoking is strictly prohibited at the work site. Maintain good hygiene habits.

Physical and chemical properties

Main Ingredients: Pure Appearance and Characteristics: Colorless and transparent liquid with an odor similar to a mixture of ethanol and acetone.

Melting point (℃): -88.5 Boiling point (℃): 80.3 Relative density (water=1): 0.79 Relative vapor density (air=1): 2.07

Saturated vapor pressure (kPa): 4.40 (20 ℃) Combustion heat (kJ/mol): 1984.7 Critical temperature (℃): 275.2 Critical pressure (MPa): 4.76

Logarithmic value of octanol/water partition coefficient:<0.28 Flash point (℃): 12 Ignition temperature (℃): 399 Explosion upper limit% (V/V): 2.0~12.7

Solubility: soluble in most organic solvents such as water, alcohol, ether, benzene, chloroform, etc.

Main use: It is an important chemical product and raw material. Mainly used in pharmaceuticals, cosmetics, plastics, fragrances, coatings, etc.

Toxicological data

LD50: 5045 mg/kg (oral administration in rats); 12800 mg/kg (rabbit transdermal) LC50: No data available

Prohibited substances: strong oxidants, acids, anhydrides, halogens.

Transportation information

Packaging method: Small opening steel drum; Ordinary wooden box outside the ampoule bottle; Screw mouth glass bottles, iron cap pressed mouth glass bottles, plastic bottles, or ordinary wooden boxes outside metal drums (cans); Threaded glass bottles, plastic bottles, or tin plated steel drums (cans) are filled with bottom plate flower boxes, fiberboard boxes, or plywood boxes.

Transportation precautions: During transportation, the transport vehicle should be equipped with corresponding types and quantities of fire-fighting equipment and emergency response equipment for leaks. It is best to transport in the morning and evening during summer. The tank truck used for transportation should have a grounding chain, and a perforated partition can be installed inside the tank to reduce static electricity generated by vibration. It is strictly prohibited to mix and transport with oxidants, acids, halogens, edible chemicals, etc. During transportation, it should be protected from direct sunlight, rain, and high temperatures. When stopping midway, one should stay away from sources of fire, heat, and high temperature areas. The exhaust pipe of the vehicle carrying the item must be equipped with a flame retardant device, and the use of mechanical equipment and tools that are prone to generating sparks for loading and unloading is prohibited. When transporting by road, follow the prescribed route and do not stay in residential or densely populated areas. It is prohibited to slip during railway transportation. It is strictly prohibited to use wooden boats or cement boats for bulk transportation.